Introduction to Organic Chemistry
Friday, February 25, 2011
Stereoisomerism
-Compounds which have the same molecular formula and structural formula but differ in arrangement of atoms in space.
-Divided into two types: cis-trans isomerism and optical isomers(enantiomers)
-Divided into two types: cis-trans isomerism and optical isomers(enantiomers)
Cis-Trans Isomerism | Optical Isomerism |
Arises due to restricted arrangement of carbon-carbon double bond and carbon-carbon single bond in cyclic compounds | Carbon molecules with at least one chirality centre(carbon attached to 4 different atoms or groups of atoms) |
Has different atoms or groups of atoms at the same C=C bond or C-C bond in cyclic compounds | Optically active, exist as enantiomers and not superimposable |
Have same chemical properties but different physical properties | Able to rotate plane polarised light in a polarimeter |
Constitutional Isomerism
-Divided into 3 types: chain, positional and functional group isomerism.
Chain Isomers | Positional Isomers | Functional Group Isomers |
Differ in number of longest carbon | Differ in position of functional group | Differ in type of class |
Differ in physical properties Similar in chemical properties | Differ in physical properties Similar in chemical properties | Differ in both physical and chemical properties |
Functional Group Isomers |
Chain Isomers |
Positional Isomers |
Isomerism
Isomers are compounds which have the same molecular formula but different structural formulae.
There are two types of isomers which in turn subdivides into other isomers as shown below:
There are two types of isomers which in turn subdivides into other isomers as shown below:
Wednesday, February 23, 2011
Introduction To Organic Chemistry
- Organic chemistry: The study of carbon compounds from living thing which contains C, H, O, S, P and halogens(F, Cl, Br, I)
- Essential in all aspects of life whether it is living or non-living matters.
- Have extensive uses in many fields such as medical, agriculture, engineering and biotechnology.
-Can be divided into several subtopics:
Empirical, molecular and structural formulae
Functional groups and homologous series
Isomerism (Covered in the next post)
Organic Reactions
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